FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000257155> ?p ?o ?g. }

• W2000257155 endingPage "114" @default.
• W2000257155 startingPage "95" @default.
• W2000257155 abstract "Über Austauschreaktionen wurden mit Rb2Na3[InO4], Cs2Na3[InO4] und Cs2Na3[TlO4] die ersten Vertreter des Typs A2A3′[MO4] mit M = In bzw. Tl und A = Rb oder Cs in Form von Einkristallen dargestellt. Rb2Na3[InO4]: farblose Einkristalle; Tempern inniger Gemenge von a-Na5InO4 und Rb2O (Rb : In = 2,8: 1; Ni-Bombe; 300°C, 2d; 620°C, 16d; orthorhombisch, Pnnm; a = 971,1 (1), b = 950,0 (1), c = 745,9 (1) pm; Z = 4; Vierkreisdiffraktometerdaten (Siemens AED 2; Mo—Kα; 9782 Io (hkl); R = 5,7%, Rw = 4,5%). Es liegt Isotypie zu Na2Li3[GaO4] und K2Na3[InO4] vor. Cs2Na3[InO4]: hellgelbe Einkristalle; Tempern inniger Gemenge von a-Na5InO4 und Cs2O (Cs : In = 5,0 : 1; Au-Rohr; 260°C, 10 d; 600°C, 30 d); monoklin (P21/c) mit a = 634,8, b = 1026,7; c = 1254,6 pm, β = 111,52°; Z = 4; Vierkreisdiffraktometerdaten (Philips PW 1100, Ag-Kα, 6506 Io(hkl), R = 8,6%, Rw = 5,5%). Es liegt Isotypie zu K2Li3[GaO4] vor. Cs2Na3[TlO4]: orangerote Einkristalle; Tempern inniger Gemenge von a-Na5TlO4 und Cs2O (Cs : Tl = 2,3 : 1; Ag-Bombe; 280°C, 3 d; 580°C, 30 d); monoklin (P21/c) mit a = 642,0, b = 1018,2, c = 1264,5 pm; β = 111,12°; Z = 4; Vierkreisdiffraktometerdaten (Philips PW 1100; Ag-Kα, 6391 Io(hkl), R = 15,4%, Rw = 9,1%). Die neue Verbindung ist isotyp zu Cs2Na3[InO4]. Der Madelunganteil der Gitterenergie, MAPLE, und die Ladungsverteilung für die drei neuen Oxide werden berechnet und diskutiert. New Examples of the A2A3′[MO4] Type: Rb2Na3[InO4], Cs2Na3[InO4], and Cs2Na3[TlO4] By exchange reactions the first examples of the A2A3′[MO4]-type with M = In, Tl and A = Rb, Cs Rb2Na3[InO4], Cs2Na3[InO4], and Cs2Na3[TlO4] were prepared in form of single crystals. Rb2Na3[InO4]: colourless single crystals; heating intimate mixtures of a-Na5InO4 and Rb2O (Rb : In = 2.8 : 1, sealed Ni-tube; 300°C, 2 d; 620°C, 16 d), orthorhombic (Pnnm) with a = 971.1 (1), b = 950.0(1), c = 745.9 (1) pm, Z = 4; four-circle diffractometer data (Siemens AED 2, Mo-Kα, 9782Io(hkl), R = 5.7%, Rw = 4.5%). The new compound is isotypic to Na2Li3[GaO4] and K2Na3[InO4]. Cs2Na3[InO4]: light yellow single crystals; heating intimate mixtures of a-Na5InO4 and Cs2O (Cs : In = 5.0 : 1, sealed Au-tube, 260°C, 10 d; 600°C, 30 d), monoclinic (P21/c) with a = 634.8, b = 1026.7, c = 1254.6 pm, β = 111.52°, Z = 4, four-circle diffractometer data (Philips PW 1100, Ag-Kα, 6506 Io(hkl), R = 8.6%, Rw = 5.5%). The new compound is isotypic to K2Li3[GaO4]. Cs2Na3[TlO4]: orange single crystals, heating intimate mixture of a-Na5TlO4 and Cs2O (Cs : Tl = 2.3 : 1, sealed Ag-tube, 280°C, 3 d; 580°C, 30 d), monoclinic (P21/c) with a = 642.0, b = 1018.2, c = 1264.5 pm, β = 111.12°, Z = 4, four-circle diffractometer data (Philips PW 1100, Ag-Kα), 6391 Io(hkl), R = 15.4%, Rw = 9.1%). The new compound is isotypic to Cs2Na3[InO4]. The Madelung part of lattice energy, MAPLE, and charge distributions for the three new oxides are calculated and discussed." @default.
• W2000257155 created "2016-06-24" @default.
• W2000257155 creator A5033826685 @default.
• W2000257155 creator A5088743319 @default.
• W2000257155 date "1991-04-01" @default.
• W2000257155 modified "2023-09-23" @default.
• W2000257155 title "Neue Vertreter des A2A3?[MO4]-Typs: Rb2Na3[InO4], Cs2Na3[InO4] und Cs2Na3[TlO4] [1]" @default.
• W2000257155 cites W1906331750 @default.
• W2000257155 cites W1969638099 @default.
• W2000257155 cites W1997766750 @default.
• W2000257155 cites W2009130511 @default.
• W2000257155 cites W2021506505 @default.
• W2000257155 cites W2022002111 @default.
• W2000257155 cites W2035564391 @default.
• W2000257155 cites W2037691532 @default.
• W2000257155 cites W2044279791 @default.
• W2000257155 cites W2054797789 @default.
• W2000257155 cites W2062753861 @default.
• W2000257155 cites W2072847811 @default.
• W2000257155 cites W2074019256 @default.
• W2000257155 cites W2075405010 @default.
• W2000257155 cites W2081754528 @default.
• W2000257155 cites W2081864626 @default.
• W2000257155 cites W2082753416 @default.
• W2000257155 cites W2093633598 @default.
• W2000257155 cites W2100073046 @default.
• W2000257155 cites W2116779643 @default.
• W2000257155 cites W2137414772 @default.
• W2000257155 cites W2146403521 @default.
• W2000257155 cites W2169908328 @default.
• W2000257155 cites W2312187508 @default.
• W2000257155 cites W2314807986 @default.
• W2000257155 cites W2315033109 @default.
• W2000257155 cites W4243035698 @default.
• W2000257155 doi "https://doi.org/10.1002/zaac.19915950111" @default.
• W2000257155 hasPublicationYear "1991" @default.
• W2000257155 type Work @default.
• W2000257155 sameAs 2000257155 @default.
• W2000257155 citedByCount "6" @default.
• W2000257155 countsByYear W20002571552012 @default.
• W2000257155 crossrefType "journal-article" @default.
• W2000257155 hasAuthorship W2000257155A5033826685 @default.
• W2000257155 hasAuthorship W2000257155A5088743319 @default.
• W2000257155 hasConcept C115624301 @default.
• W2000257155 hasConcept C185592680 @default.
• W2000257155 hasConcept C61276311 @default.
• W2000257155 hasConcept C71240020 @default.
• W2000257155 hasConcept C8010536 @default.
• W2000257155 hasConceptScore W2000257155C115624301 @default.
• W2000257155 hasConceptScore W2000257155C185592680 @default.
• W2000257155 hasConceptScore W2000257155C61276311 @default.
• W2000257155 hasConceptScore W2000257155C71240020 @default.
• W2000257155 hasConceptScore W2000257155C8010536 @default.
• W2000257155 hasIssue "1" @default.
• W2000257155 hasLocation W20002571551 @default.
• W2000257155 hasOpenAccess W2000257155 @default.
• W2000257155 hasPrimaryLocation W20002571551 @default.
• W2000257155 hasRelatedWork W1970405244 @default.
• W2000257155 hasRelatedWork W1979358532 @default.
• W2000257155 hasRelatedWork W2030390379 @default.
• W2000257155 hasRelatedWork W2081595343 @default.
• W2000257155 hasRelatedWork W2082823139 @default.
• W2000257155 hasRelatedWork W2087104096 @default.
• W2000257155 hasRelatedWork W2104742556 @default.
• W2000257155 hasRelatedWork W2262641225 @default.
• W2000257155 hasRelatedWork W2315457165 @default.
• W2000257155 hasRelatedWork W2354690460 @default.
• W2000257155 hasVolume "595" @default.
• W2000257155 isParatext "false" @default.
• W2000257155 isRetracted "false" @default.
• W2000257155 magId "2000257155" @default.
• W2000257155 workType "article" @default.