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• W2000258974 abstract "The pure rotational spectrum of AlCCH in its ground electronic state (X∼1Σ+) has been measured using Fourier transform microwave (FTMW) and mm/sub-mm direct absorption spectroscopy. AlCCH was created in a DC discharge from HCCH and aluminum vapor, either produced by a Broida-type oven, or generated from Al(CH3)3 in a supersonic jet source. Rotational transitions were measured for five isotopologues of AlCCH, with 13C and deuterium substitutions. From these data, rotational and Al and D quadrupole parameters were determined, as well as an accurate structure. AlCCH appears to exhibit an acetylenic arrangement with significant covalent character in the Al–C single bond." @default.
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• W2000258974 date "2012-11-01" @default.
• W2000258974 modified "2023-10-16" @default.
• W2000258974 title "Gas-phase rotational spectroscopy of AlCCH : A model system for organo-aluminum compounds" @default.
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• W2000258974 doi "https://doi.org/10.1016/j.cplett.2012.08.034" @default.
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