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- W2000260024 endingPage "1997" @default.
- W2000260024 startingPage "1988" @default.
- W2000260024 abstract "Aus dem photochemischen Verhalten geeignet substituierter Derivate (Diester 3a, Dicarbonsaure 3b, Bis-trifluormethyl-Derivat 3c) wird geschlossen, das im Bicyclo[3.2.2]nona-6,8-dien-Gerust 1 (n = 3) die [2π + 2π]-Cycloaddition zu 2 (n = 3) weder bei direkter noch bei sensibilisierter Lichtanregung stattfindet. Als Ersatzreaktionen werden 1,3-Alkylverschiebung (3a 6a) und Di-π-Methanumlagerung (3a 7a, 3c 8c) beobachtet. Grunde fur dieses von den niedrigeren Homologen 1 (n = 0, 1, 2) abweichende Verhalten werden diskutiert.Photoisomerisation Reactions in Bicyclo[3.2.2]nona-6,8-diene DerivativesFrom the photochemical behavior of suitably substituted derivatives (dicarboxylic ester 3a, dicarboxylic acid 3b, bis(trifluoromethyl)-derivative 3c) it is concluded, that in the bicyclo-[3.2.2]nona-6,8-diene skeleton 1 (n = 3) the [2π + 2π]-Cycloaddition to 2 (n = 3) neither by direct nor by sensitized excitation takes place. Instead 1,3-alkyl shift (3a 6a) and di-π-methane-rearrangement 3a 7a, 3c 8c) are observed. Arguments for this behavior differing from the lower homologues 1 (n = 0, 1, 2) are discussed." @default.
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- W2000260024 date "1974-06-01" @default.
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- W2000260024 title "Photoisomerisierung in Bicyclo[3.2.2]nona-6,8-dien-Derivaten" @default.
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- W2000260024 doi "https://doi.org/10.1002/cber.19741070621" @default.
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