Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000261720> ?p ?o ?g. }
- W2000261720 endingPage "3912" @default.
- W2000261720 startingPage "3901" @default.
- W2000261720 abstract "Abstract When working with capillary zone electrophoresis (CZE), the analyst has to be aware that the separation system is not homogeneous anymore as soon as a sample is brought into the background electrolyte (BGE). Upon injection, the analyte creates a disturbance in the concentration of the BGE, and the system retains a kind of memory for this inhomogeneity, which is propagated with time and leads to so‐called system zones (or system eigenzones) migrating in an electric field with a certain eigenmobility. If recordable by the detector, they appear in the electropherogram as system peaks (or system eigenpeaks). However, although their appearance can not be forecasted and explained easily, they are inherent for the separation system. The progress in the theory of electromigration (accompanied by development of computer software) allows to treat the phenomenon of system zones and system peaks now also in very complex BGE systems, consisting of several multivalent weak electrolytes, and at all pH ranges. It also allows to predict the existence of BGEs having no stationary injection zone (or water zone, EO zone, gap, dip). Our paper reviews the theoretical background of the origin of the system zones (system peaks, system eigenpeaks), discusses the validity of the Kohlrausch regulating function, and gives practical hints for preparing BGEs with good separation ability not deteriorated by the occurrence of system peaks and by excessive peak‐broadening." @default.
- W2000261720 created "2016-06-24" @default.
- W2000261720 creator A5002011879 @default.
- W2000261720 creator A5079792238 @default.
- W2000261720 date "2004-12-01" @default.
- W2000261720 modified "2023-10-09" @default.
- W2000261720 title "System zones in capillary zone electrophoresis" @default.
- W2000261720 cites W1907152296 @default.
- W2000261720 cites W1964741334 @default.
- W2000261720 cites W1967663907 @default.
- W2000261720 cites W1969070874 @default.
- W2000261720 cites W1972418571 @default.
- W2000261720 cites W1981622542 @default.
- W2000261720 cites W1981925073 @default.
- W2000261720 cites W1985924927 @default.
- W2000261720 cites W1990107160 @default.
- W2000261720 cites W1992701200 @default.
- W2000261720 cites W1993895775 @default.
- W2000261720 cites W1995935895 @default.
- W2000261720 cites W1996777451 @default.
- W2000261720 cites W1997338405 @default.
- W2000261720 cites W1998010697 @default.
- W2000261720 cites W2000701786 @default.
- W2000261720 cites W2001174127 @default.
- W2000261720 cites W2002937755 @default.
- W2000261720 cites W2006658171 @default.
- W2000261720 cites W2006856323 @default.
- W2000261720 cites W2009237050 @default.
- W2000261720 cites W2009632870 @default.
- W2000261720 cites W2010609292 @default.
- W2000261720 cites W2018612325 @default.
- W2000261720 cites W2019619475 @default.
- W2000261720 cites W2020523461 @default.
- W2000261720 cites W2021707791 @default.
- W2000261720 cites W2023029048 @default.
- W2000261720 cites W2024845529 @default.
- W2000261720 cites W2025844185 @default.
- W2000261720 cites W2025962623 @default.
- W2000261720 cites W2026183748 @default.
- W2000261720 cites W2026551289 @default.
- W2000261720 cites W2029631668 @default.
- W2000261720 cites W2030441205 @default.
- W2000261720 cites W2030585081 @default.
- W2000261720 cites W2036312364 @default.
- W2000261720 cites W2036776878 @default.
- W2000261720 cites W2038246738 @default.
- W2000261720 cites W2038870923 @default.
- W2000261720 cites W2043245153 @default.
- W2000261720 cites W2046838718 @default.
- W2000261720 cites W2048221056 @default.
- W2000261720 cites W2049974708 @default.
- W2000261720 cites W2053795961 @default.
- W2000261720 cites W2054935052 @default.
- W2000261720 cites W2063134910 @default.
- W2000261720 cites W2064708468 @default.
- W2000261720 cites W2067017218 @default.
- W2000261720 cites W2068537446 @default.
- W2000261720 cites W2070590176 @default.
- W2000261720 cites W2076286681 @default.
- W2000261720 cites W2083910962 @default.
- W2000261720 cites W2090450470 @default.
- W2000261720 cites W2115847758 @default.
- W2000261720 cites W2116093871 @default.
- W2000261720 cites W2122158127 @default.
- W2000261720 cites W2122954423 @default.
- W2000261720 cites W2139779397 @default.
- W2000261720 cites W2155898413 @default.
- W2000261720 cites W2159068283 @default.
- W2000261720 cites W2159224834 @default.
- W2000261720 cites W2171513470 @default.
- W2000261720 cites W2298926605 @default.
- W2000261720 cites W2312861048 @default.
- W2000261720 cites W2328894238 @default.
- W2000261720 cites W2332779876 @default.
- W2000261720 cites W37879439 @default.
- W2000261720 cites W4237938146 @default.
- W2000261720 cites W98094421 @default.
- W2000261720 doi "https://doi.org/10.1002/elps.200406159" @default.
- W2000261720 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15597426" @default.
- W2000261720 hasPublicationYear "2004" @default.
- W2000261720 type Work @default.
- W2000261720 sameAs 2000261720 @default.
- W2000261720 citedByCount "50" @default.
- W2000261720 countsByYear W20002617202012 @default.
- W2000261720 countsByYear W20002617202013 @default.
- W2000261720 countsByYear W20002617202015 @default.
- W2000261720 countsByYear W20002617202016 @default.
- W2000261720 countsByYear W20002617202017 @default.
- W2000261720 countsByYear W20002617202018 @default.
- W2000261720 countsByYear W20002617202019 @default.
- W2000261720 countsByYear W20002617202021 @default.
- W2000261720 countsByYear W20002617202022 @default.
- W2000261720 crossrefType "journal-article" @default.
- W2000261720 hasAuthorship W2000261720A5002011879 @default.
- W2000261720 hasAuthorship W2000261720A5079792238 @default.
- W2000261720 hasConcept C10390740 @default.
- W2000261720 hasConcept C113196181 @default.
- W2000261720 hasConcept C120665830 @default.