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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000263995> ?p ?o ?g. }

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• W2000263995 abstract "The synthesis and structural characterization of a series of palladium complexes bearing N-heterocyclic carbenes (NHC) as supporting ligands are described. The reaction of commercially available [Pd(allyl)Cl]2 and isolated or in situ generated NHC leads to monomeric palladium complexes where one NHC is bound to the metal center, as indicated by spectroscopic and single-crystal X-ray diffraction studies. The relative reactivity trend for these complexes as catalysts in aryl amination is discussed in terms of ligand steric properties, which vary as a function of imidazole-nitrogen substituents and perturbation resulting in modulation of ring planarity. The concept of buried volume is used to quantify the steric demand of each NHC in the corresponding complexes." @default.
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• W2000263995 date "2004-02-25" @default.
• W2000263995 modified "2023-09-30" @default.
• W2000263995 title "Synthetic and Structural Studies of (NHC)Pd(allyl)Cl Complexes (NHC = <i>N</i>-heterocyclic carbene)" @default.
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• W2000263995 doi "https://doi.org/10.1021/om034319e" @default.
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