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- W2000265550 abstract "Abstract This study is concerned with the influence of nonselective catalyst poisoning on bifunc- tionally catalyzed reactions in which conversions and product distributions can be limited by thermo- dynamic equilibria. The general class of such reactions has been described as “nontrivial” polyfunctional catalysis by Weisz. Of particular interest are the relationships of optimal catalyst formulation and reaction selectivity to the physical and chemical properties of the reaction system, and the comparison of deactivation effects with those in simpler reactions. It is shown that equilibrium limitations can have signal influence on deactivation rates and selectivities under certain circum- stances, which are discussed. When activity decline is compensated for by increasing the reaction temperature, probably the most important factor in determining the behavior of the reaction system is the relative, magnitude of the forward and reverse reaction activation energies." @default.
- W2000265550 created "2016-06-24" @default.
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- W2000265550 date "1970-05-01" @default.
- W2000265550 modified "2023-09-27" @default.
- W2000265550 title "Analysis of nonselective poisoning: reaction selectivity and reactor performance in some nontrivial polyfunctional systems" @default.
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- W2000265550 doi "https://doi.org/10.1016/0009-2509(70)85115-6" @default.
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