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- W2000266792 abstract "Unusual intermetallic deuteride LaNiInD1.63−x containing D…D pairs with very short D…D separations of 1.63 Å has been studied at 200 K at pressures up to 40 GPa by high-pressure synchrotron X-ray diffraction. In the elastic region (<20 GPa) the compression of LaNiInD1.63−x is close to isotropic; Δa/a=−4.1%, Δc/c=−4.3%, ΔV/V=−12.5%. At higher pressures (20<P<40 GPa) a hysteresis in the compressibility behaviour of a and c is developed. The application of high pressures results in a rather moderate reduction of the D…D separations (1.63 Å at 1.1 GPa vs. 1.47 Å at 39.5 GPa). The compressibility of the deuteride is dominated by the behaviour of the metal sublattice. Higher pressures are required to achieve further approach of H atoms to each other with a possible establishment of a H…H bonding interaction." @default.
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- W2000266792 date "2003-08-01" @default.
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- W2000266792 title "High pressure synchrotron XRD study of the pressure induced structural changes in LaNiInD1.63−x" @default.
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- W2000266792 doi "https://doi.org/10.1016/s0925-8388(02)01234-3" @default.
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