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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000267849> ?p ?o ?g. }

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• W2000267849 abstract "A novel palladium-catalyzed intramolecular aerobic oxidative allylic C-H amination of olefins has been developed. Brønsted base can modulate the regioselectivity, favoring the formation of 7-membered rings. Mechanistic studies using deuterium-labeled substrates as probes support a rate-determining allylic C-H activation/irreversible reductive elimination pathway." @default.
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• W2000267849 date "2009-05-20" @default.
• W2000267849 modified "2023-09-24" @default.
• W2000267849 title "Brønsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes: Formation of Seven-Membered Amides and Evidence for Allylic C−H Activation" @default.
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• W2000267849 doi "https://doi.org/10.1021/ol900941t" @default.
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