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- W2000272002 abstract "The polar character of the sulfinyl bond, which determines many of the properties of dimethyl sulfoxide (DMSO), is a result of charge transfer in low-lying π-type orbitals. This characteristic—together with the wide energy gap between the highest occupied and the lowest unoccupied molecular orbitals of this substance—makes DMSO a relatively inert aprotic solvent with strong nucleophilicity and electrophilicity." @default.
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- W2000272002 date "2012-06-21" @default.
- W2000272002 modified "2023-10-17" @default.
- W2000272002 title "The Chemical Bond in Carbonyl and Sulfinyl Groups Studied by Soft X-ray Spectroscopy and ab Initio Calculations" @default.
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- W2000272002 doi "https://doi.org/10.1002/cphc.201200314" @default.
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