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- W2000272076 abstract "The thermodynamic behavior of the system H2O/BSA was studied at 25 °C within the entire composition range: vapor pressure measurements via head space sampling gas chromatography demonstrate that the attainment of equilibria takes more than one week. A miscibility gap was detected via turbidity and the coexisting phases were analyzed. At 6 °C the two phase region extends from ca. 34 to 40 wt % BSA; it shrinks upon heating. The polymer rich phase is locally ordered, as can be seen under the optical microscope using crossed polarizers. The Flory–Huggins theory turns out to be inappropriate for the modeling of experimental results. A phenomenological expression is employed which uses three adjustable parameters and describes the vapor pressures quantitatively; it also forecasts the existence of a miscibility gap." @default.
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- W2000272076 date "2013-04-24" @default.
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- W2000272076 title "Liquid/Gas and Liquid/Liquid Phase Equilibria of the System Water/Bovine Serum Albumin" @default.
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- W2000272076 doi "https://doi.org/10.1021/jp4010482" @default.
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