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- W2000272812 abstract "Selected imines reacted with three different trifluoromethyl group-containing ketones in a non-catalyzed manner at ambient temperature to give the corresponding β-hydroxy-β-trifluoromethyl imines in good to excellent yields. With 1,1,1-trifluoroacetone a 1:1 and a 2:1 reaction product was obtained. The reduction of 2-isopropylimino-4-phenyl-5,5,5-trifluoropentan-4-ol led to a 5:1 diastereomeric mixture of the corresponding amine, whose dominant form was found to be (2S, 4R) 4-isopropylamino-4-phenyl-2-trifluoromethyl-butan-2-ol in the solid state. Hydrolysis in one case gave the respective β-hydroxy ketone." @default.
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- W2000272812 date "2002-01-01" @default.
- W2000272812 modified "2023-10-06" @default.
- W2000272812 title "Simple access to novel β-hydroxy-β-trifluoromethyl imines" @default.
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- W2000272812 doi "https://doi.org/10.1016/s0022-1139(01)00500-0" @default.
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