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- W2000273863 abstract "Picosecond CO recombination kinetics have been measured after photodissociation of the artificial complexes calmodulin∗ heme-CO and calmodulin∗ heme-CO∗ melittin. These systems show an enhancement of the geminate fraction of kinetics relative to unbound heme-CO, due in part to fast geminate kinetics (τ = 50 ps for the initial phase), as well as a decrease in the rate of migration of CO away from the binding site. This indicates that calmodulin provides a complete pocket around the heme group. Rather than competing with the hemes for binding to calmodulin, the melittin seems to act as a cap to further enclose the hemes; melittin increases the affinity of calmodulin for heme-CO, but only weakly affects the CO recombination kinetics." @default.
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- W2000273863 date "1996-03-01" @default.
- W2000273863 modified "2023-10-18" @default.
- W2000273863 title "Picosecond geminate recombination of CO to the complexes calmodulin∗ heme-CO and calmodulin∗ heme-CO∗ melittin" @default.
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- W2000273863 doi "https://doi.org/10.1016/0167-4838(95)00237-5" @default.
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