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- W2000276377 abstract "Die Umwandlung des Spiro[2.4]hepta-4,6-diens (1) mit Fe2(CO)9 führt unter Öffnung des Dreirings und CO-Einschiebung zum überbrückten η1-Acyl-η5-cyclopentadienyl-Komplex 3, der bei der Einwirkung von weiterem Fe2(CO)9 unter Decarbonylierung, Einschub einer Fe(CO)4 -Einheit und H-Verschiebung über die labile Zwischenstufe 6 zu dem vom Methylfulven abgeleiteten Zweikernkomplex 4 weiterreagiert. Ring Opening Conversions of the Spiro[2.4]hepta-4,6-diene System with Iron Carbonyls Opening of the three-membered ring of spiro[2.4]hepta-4,6-diene (1) by Fe2(CO)9 and CO insertion leads to the bridged η1-acyl-η5-cyclopentadienyl complex 3, which with additional Fe2(CO)9 via the labile intermediate 6 forms the dinuclear methylfulvene complex 4 by decarbonylation, insertion of a Fe(CO)4 unit, and hydrogen migration." @default.
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- W2000276377 date "1980-06-01" @default.
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- W2000276377 title "Ringöffnende Umwandlungen des Spiro[2.4]hepta‐4,6‐dien‐Systems mit Eisencarbonylen" @default.
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- W2000276377 doi "https://doi.org/10.1002/cber.19801130616" @default.
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