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- W2000277204 abstract "Experiments with 4-methyl[3,5,6-2H3]pyrocatechol 7 have shown that the product of its enzymic oxygenation, 3-methyl-cis,cis-muconic acid 8, undergoes enzymic cyclisation by syn addition of carboxy groups to distal double bonds to form the (S)-4-methylmuconolactone 9 in the bacterium Pseudomonas putida and the (S)-3-methylmuconolactone 11 in the fungus Aspergillus niger. Similarly, syn cyclisation of the cis,cis-muconic acid 15 has been shown to occur in A. niger to form the (S)-muconolactone 16. The relative and absolute stereochemistries of enzymic cycloisomerisation of muconic, 3-carboxymuconic and 3-methylmuconic acid in bacteria and fungi are here compared and discussed." @default.
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- W2000277204 date "1996-01-01" @default.
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- W2000277204 title "Stereochemistry of the enzymic lactonisation of cis,cis-muconic and 3-methyl-cis,cis-muconic acid" @default.
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- W2000277204 doi "https://doi.org/10.1039/p19960001153" @default.
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