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• W2000284420 abstract "Oligomer of styrene and maleic anhydride synthesized by bulk RAFT polymerization (SMA-RAFT) was used to construct a novel strategy for robust nanoencapsulation via interfacially confined controlled/living radical miniemulsion polymerization. After ammonolysis, SMA-RAFT becomes amphiphilic and can be used as a surfactant to prepare miniemulsion. The ammonolyzed SMA-RAFT molecules would self-assemble on the interface of water/droplets. This self-assembly property combining with the RAFT living polymerization chemistry demands the polymer chains to grow inwards gradually in particles, leading to the formation of a polymer shell. The hydrophilicity of ammonolyzed SMA-RAFT agent tuned by the ammonolyzed degree or structures of SMA-RAFT agent was found to play a key role in the final morphology. The well-defined nanocapsules with little solid particles can be obtained by using partially ammonolyzed SMA-RAFT with 0.5 wt% SDS as a co-surfactant." @default.
• W2000284420 created "2016-06-24" @default.
• W2000284420 creator A5059109137 @default.
• W2000284420 creator A5090668389 @default.
• W2000284420 date "2007-05-01" @default.
• W2000284420 modified "2023-10-16" @default.
• W2000284420 title "Nanoencapsulation via interfacially confined reversible addition fragmentation transfer (RAFT) miniemulsion polymerization" @default.
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• W2000284420 doi "https://doi.org/10.1016/j.polymer.2007.03.042" @default.
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