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• W2000285888 startingPage "223504" @default.
• W2000285888 abstract "The structural and optical properties of pentenary alloy (Ag,Cu)(In,Ga)Se2 polycrystalline thin films were characterized over the entire compositional range at a fixed (Cu + Ag)/(In + Ga) ratio. Films deposited at 550 °C on bare and molybdenum coated soda-lime glass by elemental co-evaporation in a single-stage process with constant incident fluxes exhibit single phase chalcopyrite structure, corresponding to 122 spacegroup (I-42d) over the entire compositional space. Unit cell refinement of the diffraction patterns show that increasing Ag substitution for Cu, the refined ao lattice constant, (Ag,Cu)-Se bond length, and anion displacement increase in accordance with the theoretical model proposed by Jaffe, Wei, and Zunger. However, the refined co lattice constant and (In,Ga)-Se bond length deviated from theoretical expectations for films with mid-range Ag and Ga compositions and are attributed to influences from crystallographic bond chain ordering or cation electronegativity. The optical band gap, derived from transmission and reflection measurements, widened with increasing Ag and Ga content, due to influences from anion displacement and cation electronegativity, as expected from theoretical considerations for pseudo-binary chalcopyrite compounds." @default.
• W2000285888 created "2016-06-24" @default.
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• W2000285888 date "2014-06-14" @default.
• W2000285888 modified "2023-10-02" @default.
• W2000285888 title "Structural and optical properties of (Ag,Cu)(In,Ga)Se₂polycrystalline thin film alloys" @default.
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• W2000285888 doi "https://doi.org/10.1063/1.4880243" @default.
• W2000285888 hasPublicationYear "2014" @default.
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