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- W2000287678 abstract "New kinetic data on the Vilsmeier–Haack reaction of heterocyclic compounds are reported which permit the conclusions that (i) the reaction is very selective, as shown by a ρ value of –7·3 for the formylation of thiophen derivatives in chloroform, (ii) the rate of substitution is only affected to a small extent by the polarity of the solvent, and (iii) the rate of substitution is highly dependent on the nature of amide. The reaction with NN-dimethylacetamide–carbonyl chloride complex proceeds ca. 5 × 103 times slower than the reaction with corresponding NN-dimethylformamide complex." @default.
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- W2000287678 date "1974-01-01" @default.
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- W2000287678 title "The mechanism of the Vilsmeier–Haack reaction. Part III. Structural and solvent effects" @default.
- W2000287678 doi "https://doi.org/10.1039/p29740001610" @default.
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