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- W2000290253 abstract "Measurements have been made of the heat capacity Cp from ∼13 to ∼ 298°K of three clathrates of methane and β-quinol, in which 75·5, 45·7 and 16·5 per cent of the cavities were occupied by methane. Over the entire temperature range Cp is found to be a linear function of composition. The contribution made to the heat capacity by a mole of methane has been analysed with the aid of the theory of J. H. van der Waals, and the rotational contribution found to be 3/2R, within experimental error, from about 150°k upwards, showing that rotation of the methane molecules is almost unrestricted. The heats of formation of several methane clathrates have also been measured calorimetrically." @default.
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- W2000290253 date "1960-01-01" @default.
- W2000290253 modified "2023-09-24" @default.
- W2000290253 title "Thermodynamic properties of clathrates: II. The heat capacity and entropy of methane in the methane quinol clathrates" @default.
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- W2000290253 doi "https://doi.org/10.1080/00268976000100061" @default.
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