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• W2000292954 abstract "Abstract We have investigated the correlation between the macroscopic physical properties and the microscopic molecular structure for linear rod-like polyamides with different linking structure of nonlinear optical chromophores by in situ corona poling and optical second harmonic generation. These polymers consist of a wholly aromatic rigid backbone poly( p -phenylene terephthalamide), PPTA and nonlinear optical chromophores of various sizes. Though all polymers with different linking structure of chromophores possess similar α- and β-glass transition temperatures, their bulk physical properties greatly depend on the microscopic linking structure. Especially the polyamide F-DCVA with a flexibly linked bulky chromophore exhibits a high internal stress due to a thermal contraction of the rigid polyamide backbone, which at room temperature can overcome the orientational force of the externally applied electric field." @default.
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• W2000292954 date "2007-03-01" @default.
• W2000292954 modified "2023-10-14" @default.
• W2000292954 title "Polar ordering of linear rod-like polyamide with different linking structure of nonlinear optical chromophores" @default.
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• W2000292954 doi "https://doi.org/10.1016/j.optmat.2006.01.005" @default.
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