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- W2000294527 abstract "Abstract The dehydrogenation of 1,2,3,4-tetrahydronaphthalene (tetralin) to naphthalene with 2,3-dichloro-5,6-dicyano-quinone (DDQ.) involves 1,2-dihydronaphthalene as an intermediate. The kinetic, the secondary, and the intramolecular isotope effects in the conversion of (1- 3 H )tetralin to 1,2-dihydro-(4- 3 H )naphthalene and of 1,2-dihydro-(1- 3 H )naphthalene to (1- 3 H )naphthalene have been determined. The isotope effects involved in both conversions were of the same order of magnitude, the intramolecular effect being 10 and 23, the kinetic effect 2·1 and 2·4 and the secondary effect 0·9 and 0·8 in the first and second conversion, respectively. These data indicate the α-hydrogen abstraction as the rate determining step in accordance with the proposed hydride transfer mechanism." @default.
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- W2000294527 date "1971-01-01" @default.
- W2000294527 modified "2023-09-24" @default.
- W2000294527 title "Tritium isotope effects in the oxidation of 1,2,3,4-tetrahydro-(1-3H)naphthalene to (1-3H)naphthalene by 2,3-dichloro-5,6-dicyano-quinone (DDQ)" @default.
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- W2000294527 doi "https://doi.org/10.1016/s0040-4020(01)98112-8" @default.
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