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- W2000295090 abstract "Synthesis of Terminal Acetylenic Sugars Derivatives and Ynuronic Acids Derivatives by Use of a Wittig Reaction The method described for the preparation of terminal acetylenic sugars presents two advantages over earlier procedures: no new asymmetric center is created and the chain can be extended by one or more C-atoms. The method also allows preparation of ynuronic acids. The aldehydosugars derivatives 1–7 gave in good to excellent yields the corresponding gem-dibromoenoses 8–14 from which either the terminal acetylenic sugars derivatives 15–21 or the ynuronic acids 22–24 were easily prepared. A few examples of 1,3-dipolar cycloadditions (leading to 28–30) with these acetylenic sugar derivatives are also described." @default.
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- W2000295090 date "1980-07-09" @default.
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- W2000295090 title "Préparation de dérivés de sucres acétyléniques terminaux et d'acides ynuroniques par réaction de<i>Wittig</i>. Note de laboratoire" @default.
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- W2000295090 doi "https://doi.org/10.1002/hlca.19800630509" @default.
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