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- W2000295401 abstract "The enantioselective synthesis of α-hydroxy esters by ruthenium-catalyzed 1,2-addition of arylboronic acids to tert-butyl glyoxylate is described. The use of RuCl2(PPh3)3 with (R,R)-Me-BIPAM gave optically active mandelic acids of up to 99% ee. Addition of a fluoride salt such as potassium fluoride (KF) or caesium fluoride (CsF) was effective for achieving high enantioselectivities." @default.
- W2000295401 created "2016-06-24" @default.
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- W2000295401 date "2012-01-01" @default.
- W2000295401 modified "2023-10-06" @default.
- W2000295401 title "Asymmetric addition of arylboronic acids to glyoxylate catalyzed by a ruthenium/Me-BIPAM complex" @default.
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- W2000295401 doi "https://doi.org/10.1039/c2cc17339e" @default.
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