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- W2000298035 abstract "New N-alkyl-3,5-pyrazole derived ligands were synthesized by reaction between 3,5-pyrazole derived ligands and the appropriate haloalkane in toluene or THF using NaOEt or NaH as base. When the precursor ligand bears a pyridyl substituent the alkylation reaction presents a large regioselectivity. Theoretical calculations have been carried out to rationalize the experimental observations. It has been shown that regioselectivity is governed by the formation of Na+-pyrazolide chelate complexes." @default.
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- W2000298035 date "2005-12-01" @default.
- W2000298035 modified "2023-10-11" @default.
- W2000298035 title "Regioselective formation of N-alkyl-3,5-pyrazole derived ligands. A synthetic and computational study" @default.
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- W2000298035 doi "https://doi.org/10.1016/j.tet.2005.09.085" @default.
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