Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000299071> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2000299071 endingPage "2279" @default.
- W2000299071 startingPage "2271" @default.
- W2000299071 abstract "A previously described procedure for coating electrodes with multiple layers of heteropolyanions and charge-balancing dipositive cations[1]was extended to incorporate catalytically active reactants in the coatings. Clear electrocatalytic activity was demonstrated for both anionic ([P2Mo18O62]6−) and cationic ([cis-Ru(dcbpy)2(OH2)2]2+ (dcbpy=6,6′-dichloro-2,2′-bipyridine)) components of coatings on roughly polished edge plane pyrolytic graphite electrodes. However, the stacking of multilayers on top of the first layer of [P2Mo18O62]6− adsorbed on the electrode produced almost no increase in catalytic currents for the reduction of HNO2 to N2O and the activity of [cis-Ru(dcbpy)2(OH2)2]2+ in coatings toward the catalytic oxidation of benzyl alcohol was short-lived. The behavior observed provided insight into the features that must be controlled to obtain useful coatings consisting of multilayers of electrocatalysts. The kinetics of the reduction of HNO2 by [H2P2Mo18O62]6− with both reactants present in solution were also examined. The reaction produces N2O and a rate constant for the process of 3.5×102 M−1 s−1 was estimated from rotating disk voltammetric measurements. O2 does not react with the reduced complex, [H2Mo18O62]6−, but during its reaction with HNO2 any O2 also present undergoes catalytic reduction. The intermediate proposed to be involved in both catalytic reactions is an adduct formed by the reaction of HNO2 with [H2P2Mo18O62]6−." @default.
- W2000299071 created "2016-06-24" @default.
- W2000299071 creator A5002741099 @default.
- W2000299071 creator A5051925552 @default.
- W2000299071 date "1999-02-01" @default.
- W2000299071 modified "2023-10-18" @default.
- W2000299071 title "Electrochemical reduction of HNO2 or oxidation of benzyl alcohol by electrocatalyst coatings consisting of alternating layers of [P2Mo18O62]6− anions and Os(II)- or Ru(II)-polypyridine cations" @default.
- W2000299071 cites W1967309570 @default.
- W2000299071 cites W1973431496 @default.
- W2000299071 cites W19768748 @default.
- W2000299071 cites W1979308234 @default.
- W2000299071 cites W1979691818 @default.
- W2000299071 cites W1989239727 @default.
- W2000299071 cites W1994798889 @default.
- W2000299071 cites W1995562839 @default.
- W2000299071 cites W2016073373 @default.
- W2000299071 cites W2026866856 @default.
- W2000299071 cites W2041243041 @default.
- W2000299071 cites W2045980840 @default.
- W2000299071 cites W2059361276 @default.
- W2000299071 cites W2090462077 @default.
- W2000299071 cites W2312581877 @default.
- W2000299071 cites W243187772 @default.
- W2000299071 cites W2949626903 @default.
- W2000299071 cites W330008165 @default.
- W2000299071 cites W4237724529 @default.
- W2000299071 cites W4243201695 @default.
- W2000299071 doi "https://doi.org/10.1016/s0013-4686(98)00344-2" @default.
- W2000299071 hasPublicationYear "1999" @default.
- W2000299071 type Work @default.
- W2000299071 sameAs 2000299071 @default.
- W2000299071 citedByCount "37" @default.
- W2000299071 countsByYear W20002990712016 @default.
- W2000299071 crossrefType "journal-article" @default.
- W2000299071 hasAuthorship W2000299071A5002741099 @default.
- W2000299071 hasAuthorship W2000299071A5051925552 @default.
- W2000299071 hasConcept C147789679 @default.
- W2000299071 hasConcept C161790260 @default.
- W2000299071 hasConcept C17525397 @default.
- W2000299071 hasConcept C178790620 @default.
- W2000299071 hasConcept C179104552 @default.
- W2000299071 hasConcept C185592680 @default.
- W2000299071 hasConcept C2776460118 @default.
- W2000299071 hasConcept C2777869211 @default.
- W2000299071 hasConcept C2778517698 @default.
- W2000299071 hasConcept C2778931688 @default.
- W2000299071 hasConcept C33989665 @default.
- W2000299071 hasConcept C36759035 @default.
- W2000299071 hasConcept C52859227 @default.
- W2000299071 hasConcept C6775980 @default.
- W2000299071 hasConceptScore W2000299071C147789679 @default.
- W2000299071 hasConceptScore W2000299071C161790260 @default.
- W2000299071 hasConceptScore W2000299071C17525397 @default.
- W2000299071 hasConceptScore W2000299071C178790620 @default.
- W2000299071 hasConceptScore W2000299071C179104552 @default.
- W2000299071 hasConceptScore W2000299071C185592680 @default.
- W2000299071 hasConceptScore W2000299071C2776460118 @default.
- W2000299071 hasConceptScore W2000299071C2777869211 @default.
- W2000299071 hasConceptScore W2000299071C2778517698 @default.
- W2000299071 hasConceptScore W2000299071C2778931688 @default.
- W2000299071 hasConceptScore W2000299071C33989665 @default.
- W2000299071 hasConceptScore W2000299071C36759035 @default.
- W2000299071 hasConceptScore W2000299071C52859227 @default.
- W2000299071 hasConceptScore W2000299071C6775980 @default.
- W2000299071 hasIssue "13" @default.
- W2000299071 hasLocation W20002990711 @default.
- W2000299071 hasOpenAccess W2000299071 @default.
- W2000299071 hasPrimaryLocation W20002990711 @default.
- W2000299071 hasRelatedWork W1001044143 @default.
- W2000299071 hasRelatedWork W1997986742 @default.
- W2000299071 hasRelatedWork W2042715759 @default.
- W2000299071 hasRelatedWork W2131631219 @default.
- W2000299071 hasRelatedWork W2315523761 @default.
- W2000299071 hasRelatedWork W2375410627 @default.
- W2000299071 hasRelatedWork W2376106512 @default.
- W2000299071 hasRelatedWork W2472735067 @default.
- W2000299071 hasRelatedWork W2797478138 @default.
- W2000299071 hasRelatedWork W3054872367 @default.
- W2000299071 hasVolume "44" @default.
- W2000299071 isParatext "false" @default.
- W2000299071 isRetracted "false" @default.
- W2000299071 magId "2000299071" @default.
- W2000299071 workType "article" @default.