Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000301663> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W2000301663 endingPage "125" @default.
- W2000301663 startingPage "120" @default.
- W2000301663 abstract "The syntheses of CpM(i-PrDAB)2 (M = Nb, Ta; Cp = (C5H5); i-PrDAB = bis-isopropyl-1,4-diazabuta-1,3-diene) are reported. Both show fluxional NMR spectra indicating that the two DAB rings differ. The X-ray crystal structure of CpNb(i-PrDAB)2 shows one ring to be more folded than the other. Density functional calculations have been used to investigate the degree of folding of the chelate ring in the compounds Cp2M(R-DAB), (M = Ti, Zr, Hf, Nb, Ta; R = H, i-Pr; DAB = 1,4-diazabuta-1,3-diene) and CpM(R-DAB)2 (M = Nb and Ta). For Cp2M(R-DAB) the group 4 compounds all have folded rings whereas the Nb and Ta compounds have planar rings. In all compounds the rings are reduced and the folding is driven by the electron number requirements of the metal centre." @default.
- W2000301663 created "2016-06-24" @default.
- W2000301663 creator A5014321757 @default.
- W2000301663 creator A5020586971 @default.
- W2000301663 creator A5034890963 @default.
- W2000301663 creator A5063006470 @default.
- W2000301663 date "2011-04-01" @default.
- W2000301663 modified "2023-09-25" @default.
- W2000301663 title "Ring folding in cyclopentadienyl diazabutadiene complexes of group 4 and 5 transition metals" @default.
- W2000301663 cites W1553722675 @default.
- W2000301663 cites W166779064 @default.
- W2000301663 cites W1889685237 @default.
- W2000301663 cites W1982793312 @default.
- W2000301663 cites W2030687437 @default.
- W2000301663 cites W2033525977 @default.
- W2000301663 cites W2034547102 @default.
- W2000301663 cites W2038075791 @default.
- W2000301663 cites W2038533471 @default.
- W2000301663 cites W2042306496 @default.
- W2000301663 cites W2053821173 @default.
- W2000301663 cites W2066370105 @default.
- W2000301663 cites W2086957099 @default.
- W2000301663 cites W2099839601 @default.
- W2000301663 cites W2104376144 @default.
- W2000301663 cites W2112010031 @default.
- W2000301663 cites W2126952850 @default.
- W2000301663 cites W2142015702 @default.
- W2000301663 cites W2142983988 @default.
- W2000301663 cites W2143803583 @default.
- W2000301663 doi "https://doi.org/10.1016/j.ica.2011.01.014" @default.
- W2000301663 hasPublicationYear "2011" @default.
- W2000301663 type Work @default.
- W2000301663 sameAs 2000301663 @default.
- W2000301663 citedByCount "9" @default.
- W2000301663 countsByYear W20003016632012 @default.
- W2000301663 countsByYear W20003016632015 @default.
- W2000301663 countsByYear W20003016632016 @default.
- W2000301663 countsByYear W20003016632017 @default.
- W2000301663 countsByYear W20003016632020 @default.
- W2000301663 countsByYear W20003016632021 @default.
- W2000301663 countsByYear W20003016632022 @default.
- W2000301663 crossrefType "journal-article" @default.
- W2000301663 hasAuthorship W2000301663A5014321757 @default.
- W2000301663 hasAuthorship W2000301663A5020586971 @default.
- W2000301663 hasAuthorship W2000301663A5034890963 @default.
- W2000301663 hasAuthorship W2000301663A5063006470 @default.
- W2000301663 hasConcept C104264131 @default.
- W2000301663 hasConcept C106773901 @default.
- W2000301663 hasConcept C115624301 @default.
- W2000301663 hasConcept C119599485 @default.
- W2000301663 hasConcept C127413603 @default.
- W2000301663 hasConcept C155647269 @default.
- W2000301663 hasConcept C161790260 @default.
- W2000301663 hasConcept C178790620 @default.
- W2000301663 hasConcept C181458950 @default.
- W2000301663 hasConcept C185592680 @default.
- W2000301663 hasConcept C2776545253 @default.
- W2000301663 hasConcept C2780378348 @default.
- W2000301663 hasConcept C2781311116 @default.
- W2000301663 hasConcept C71240020 @default.
- W2000301663 hasConcept C8010536 @default.
- W2000301663 hasConceptScore W2000301663C104264131 @default.
- W2000301663 hasConceptScore W2000301663C106773901 @default.
- W2000301663 hasConceptScore W2000301663C115624301 @default.
- W2000301663 hasConceptScore W2000301663C119599485 @default.
- W2000301663 hasConceptScore W2000301663C127413603 @default.
- W2000301663 hasConceptScore W2000301663C155647269 @default.
- W2000301663 hasConceptScore W2000301663C161790260 @default.
- W2000301663 hasConceptScore W2000301663C178790620 @default.
- W2000301663 hasConceptScore W2000301663C181458950 @default.
- W2000301663 hasConceptScore W2000301663C185592680 @default.
- W2000301663 hasConceptScore W2000301663C2776545253 @default.
- W2000301663 hasConceptScore W2000301663C2780378348 @default.
- W2000301663 hasConceptScore W2000301663C2781311116 @default.
- W2000301663 hasConceptScore W2000301663C71240020 @default.
- W2000301663 hasConceptScore W2000301663C8010536 @default.
- W2000301663 hasIssue "1" @default.
- W2000301663 hasLocation W20003016631 @default.
- W2000301663 hasOpenAccess W2000301663 @default.
- W2000301663 hasPrimaryLocation W20003016631 @default.
- W2000301663 hasRelatedWork W15120608 @default.
- W2000301663 hasRelatedWork W1977287059 @default.
- W2000301663 hasRelatedWork W1985165372 @default.
- W2000301663 hasRelatedWork W1987891314 @default.
- W2000301663 hasRelatedWork W1989721334 @default.
- W2000301663 hasRelatedWork W1999267362 @default.
- W2000301663 hasRelatedWork W2000301663 @default.
- W2000301663 hasRelatedWork W2040296340 @default.
- W2000301663 hasRelatedWork W2080162251 @default.
- W2000301663 hasRelatedWork W2607320909 @default.
- W2000301663 hasVolume "369" @default.
- W2000301663 isParatext "false" @default.
- W2000301663 isRetracted "false" @default.
- W2000301663 magId "2000301663" @default.
- W2000301663 workType "article" @default.