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- W2000301966 abstract "Two copper(II) complexes, cluster 1, and mononuclear 2, have been synthesized by reacting acetylacetone and benzohydrazide (1:1 ratio for 1 and 1:2 ratio for 2 ) with CuCl 2 in a methanol solution. In 2 , which is a new complex, the ligand acts as a tetradentate which binds the metal ion via two amide-O atoms and two imine-N atoms providing an N 2 O 2 square-planar around the copper(II) ion. The absorption spectra data evidence strongly suggested that the two copper(II) compounds could interact with CT-DNA (intrinsic binding constant, K b = 0.45×10 4 M - 1 for 1 and K b = 2.39×10 4 M - 1 for 2 ). The super coiled plasmid pBR322 DNA cleavage ability was studied with 1 and 2 in the presence and absence of H 2 O 2 as an oxidant. In both the absence and the presence of an oxidizing agent, complex 2 exhibited no nuclease activity. However, even in the absence of an oxidant, complex 1 exhibited significant DNA cleavage activity." @default.
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- W2000301966 date "2015-03-15" @default.
- W2000301966 modified "2023-09-25" @default.
- W2000301966 title "Synthesis, structure characterization, DNA binding, and cleavage properties of mononuclear and tetranuclear cluster of copper(II) complexes" @default.
- W2000301966 cites W2282054059 @default.
- W2000301966 doi "https://doi.org/10.17344/acsi.2014.797" @default.
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