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- W2000307569 abstract "Activity coefficients for the mixed system NaCl + NaHSucc + H2O (where Succ stands for the succinate anion) are determined from emf measurements. In all cases, the stoichiometric ionic strength was kept constant at 0.1, 0.5, 1, 2 and 3 mol kg−1, and the temperature at 25°C. At each ionic strength, different ionic strength fractions, yB = mB/(mA + mB), are studied. The results obtained were analyzed by means of various theoretical or empiric-theoretical models (Harned, Scatchard-Rush-Johnson and Pitzer). From these, it can be deduced that some ionic association must have taken place in this system in which the presence of the HSucc anions play an important role. So, not only the (HSucc):- dimers, but also the triple interactions between like-charged ions (CI-HSucc-HSucc) and the less important interactions between unlike-charged ions (Na-CI- HSucc) must be taken into account in this system, if the experimental results within the experimental error are to fit properly. Because the original Pitzer model does not consider these triple interactions, it cannot adequately describe the behaviour of this mixed electrolyte and, therefore, the Chan and Khoo extension of this equation must be used." @default.
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- W2000307569 date "1989-10-01" @default.
- W2000307569 modified "2023-10-13" @default.
- W2000307569 title "Ionic Interactions in Aqueous Solutions of Organic Electrolytes: The System NaCl + NaHSucc + H2O at 25°C" @default.
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- W2000307569 doi "https://doi.org/10.1002/bbpc.19890931013" @default.
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