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- W2000313300 abstract "The capillary electrophoretic separation of noncharged enantiomers with single-isomer anionic resolving agents is reexamined here with the help of the charged resolving agent migration model. Two general model parameters have been identified that influence the effective mobility, separation selectivity and mobility difference curves of the enantiomers: parameter b, called binding selectivity (KRCD/KSCD), and parameter s, called size selectivity (μORCD/μOSCD). Analysis of the model in terms of these parameters indicates that in addition to the known, previously observed separation selectivity vs. resolving agent concentration patterns, a new pattern, increasing separation selectivity with increasing resolving agent concentration, is also possible provided that (i) KRCD/KSCD<1 and μORCD/μOSCD>1 and (KRCDμORCD)/(KSCDμOSCD)>1, or (ii) KRCD/KSCD>1 and μORCD/μOSCD<1 and (KRCDμORCD)/(KSCDμOSCD)<1. This hitherto unseen separation selectivity pattern was experimentally verified during the capillary electrophoretic separation of the enantiomers of O-isopropyl p-nitrophenyl methylphosphonate with the single-isomer octakis(2,3-diacetyl-6-sulfato)-γ-cyclodextrin as resolving agent." @default.
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- W2000313300 date "2000-09-01" @default.
- W2000313300 modified "2023-10-18" @default.
- W2000313300 title "Experimental verification of a predicted, previously unseen separation selectivity pattern in the capillary electrophoretic separation of noncharged enantiomers by octakis(2,3-diacetyl-6-sulfato)-γ-cyclodextrin" @default.
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- W2000313300 doi "https://doi.org/10.1002/1522-2683(20000901)21:15<3249::aid-elps3249>3.0.co;2-c" @default.
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