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• W2000313812 abstract "The effect of post synthesis modification was studied on cobalt impregnated mesoporous materials having different textural properties. The supports were SBA-15 and MCM-41 with conventional and spherical morphology. The modified materials were investigated by X-ray diffraction (XRD), transmission electron microscopy (TEM), temperature-programmed reduction (TPR), FT-IR spectroscopy of adsorbed probe molecules (pyridine and CO) and toluene hydrogenation as a catalytic test reaction. It was found that the amount of surface silanol groups of the mesoporous supports and the variation of the pretreatment procedure have a notable influence on the nature of the cobalt oxide species formed upon the precursor decomposition. Formation of Co3O4, CoO and Co2+ species in different ratio, depending on the mesoporous support, was established. The strength of interaction with the support determines the dispersion, reducibility and the catalytic activity in toluene hydrogenation." @default.
• W2000313812 created "2016-06-24" @default.
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• W2000313812 date "2008-04-01" @default.
• W2000313812 modified "2023-10-06" @default.
• W2000313812 title "Cobalt-containing mesoporous silicas—Preparation, characterization and catalytic activity in toluene hydrogenation" @default.
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• W2000313812 doi "https://doi.org/10.1016/j.apcata.2007.12.017" @default.
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