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- W2000316461 abstract "All possible symmetric bi-1,10-phenanthrolines (biphens) were synthesized by Ni-catalyzed coupling of corresponding halo-1,10-phenanthrolines. Their absorption and emission spectra were compared with those of phenanthroline as the reference compound. The spectral feature is explained by the molecular conformation, namely, coplanar 2,2'- and 3,3'-biphens and nearly bisected 4,4'- and 5,5'-biphens. The effects of additives, H + or Zn 2 + , on the electronic spectra varied depending on the biphen ligand. The 2,2'-ligand formed a helical complex with Cu + ions in a 2:2 ratio as revealed by spectroscopic titration and X-Ray analysis." @default.
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- W2000316461 date "2005-01-01" @default.
- W2000316461 modified "2023-09-23" @default.
- W2000316461 title "Syntheses, Spectroscopic Properties, and Cu(I) Complexes of All Possible Symmetric Bi-1,10-phenanthrolines" @default.
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- W2000316461 doi "https://doi.org/10.3987/com-04-10273" @default.
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