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- W2000320020 abstract "Aus dem Lithiumkomplex des Boranato-bis(dimethylphosphoniummethylid)-Liganden [CH2(CH3)2PBH2P(CH3)2CH2]⊖ sind mit [(CH3)2 AuCI]2 and (CO)AuCl die Dimethylgold (III)-und Gold(I)-Verbindungen 3,4 mit sechs- bzw. zwölfgliedrigen Metallocyclen erhältlich. Die Röntgenbeugungsanalyse des Komplexes 3 zeigt eine symmetrische Sesselkonformation des sechs gliedrigen Ringsystems bei quadratisch-planarer Koordination des Goldatoms. Synthesis and Crystal Structure of Boranato -bis(dimethylphosphonium methylide) Complexes of Gold Containing Six- and Twelve-membered Metallocycles The reactions of lithium boranato-bis(dimethylphosphonium methylide), Li⊖ [CH2(CH3)2-PBH2P(CH3)2]⊖, with [(CH3)2AuCl]2 and (CO)AuCl yield the dimethylgold(III) and gold(I) complexes 3,4 containing a six-and a twelve membered metallocycle, respectively. For 3, X-ray diffraction shows a chair conformation of the six-membered ring with a square planar array of ligands at the gold center." @default.
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- W2000320020 date "1981-02-01" @default.
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- W2000320020 title "Synthese und Kristallstrukturanalyse von Boranato-bis(dimethyl-phosphoniummethylid)-Komplexen des Golds mit sechs- und zwölfgliedrigem Metallocyclus" @default.
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- W2000320020 doi "https://doi.org/10.1002/cber.19811140205" @default.
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