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- W2000320428 abstract "A unique coordinated molecular capsule compound is synthesized and characterized by X-ray diffraction. The compound crystallizes in cubic space group of Pa-3 with a=14.348(1), b=14.348(1), c=14.348(1)Å, V=2953.8(4)Å3, Z=8. The diazabicyclo[2.2.2]octane-1,4-diium is occluded in the cubic anionic coordinated framework of K+ and (ClO4)− in a dimension of 7.174(1) Å, and assumes ordered feature. All of hydrogen atoms take parts in trifurcated hydrogen bonds of N–H⋯O and C–H⋯O type, respectively, the later being reported for the first time. The IR spectrum of the title compound shows significant shift of CH2 vibrational bands, and are correlated with X-ray structural data." @default.
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- W2000320428 date "2003-11-01" @default.
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- W2000320428 title "Diazabicyclo[2.2.2]octane-1,4-diium occluded in cubic anionic coordinated framework: the role of trifurcated hydrogen bonds of N–H⋯O and C–H⋯O" @default.
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- W2000320428 doi "https://doi.org/10.1016/s0022-2860(03)00530-1" @default.
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