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- W2000320460 abstract "In this article, we report the fluorescence emission of Disperse Red 1 in solution at room temperature and pumping at 532 nm with a 25 mW diode laser. We have measured its fluorescence quantum yield in methanol, ethylene glycol, glycerol, and phenol obtaining values as high as 10-3 in the aliphatic alcohols. The excitation spectra of Disperse Red 1 in all four solvents as well as its excitation anisotropy in glycerol are presented. Applying a Gaussian decomposition method to the absorption spectra along with the support from the excitation spectra, the positions of the different transitions in this pseudo-stilbene azobenzene dye were determined. Solvatochromic and isomerization constraint effects are discussed. Calculations using density functional theory at TD-B3LYP/6-31G*//HF/6-31G* level were performed to interpret the experimental observations." @default.
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- W2000320460 date "2007-12-29" @default.
- W2000320460 modified "2023-09-24" @default.
- W2000320460 title "Fluorescence Emission of Disperse Red 1 in Solution at Room Temperature" @default.
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- W2000320460 doi "https://doi.org/10.1021/jp076026v" @default.
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