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- W2000320624 abstract "Abstract Novel rhenium isothiocyanato complexes have been prepared by ligand exchange procedures starting from [ReNCl 2 (Ph 3 P) 2 ] and KSCN. The reaction with KSCN yields the rhenium(V) nitrido complex [ReN(NCS) 2 (Ph 3 P) 2 ]. [ReN(NCS) 2 (CH 3 CN)(Ph 3 P) 2 ]· CH 3 CN has been prepared by the reaction of [ReN(NCS) 2 (Ph 3 P) 2 ] with CH 3 CN. Both complexes are air-stable. They have been characterized spectroscopically. The crystal and molecular structure of [ReN(NCS) 2 (CH 3 CN)(Ph 3 P) 2 ]·CH 3 CN has been determined by single-crystal X-ray diffraction. [ReN(NCS) 2 (CH 3 CN)(Ph 3 P) 2 ]·CH 3 CN crystallizes in the monoclinic space group P 2 1 / n ( a =9.242(3), b =18.506(3), c =21.773(6) A, β=93.84(2)° with Z =4. The final R value is 0.042. The compound consists of discrete [ReN(NCS) 2 (CH 3 CN)(Ph 3 P) 2 ] molecules with an additional CH 3 CN solvent molecule per complex in the crystal lattice. The coordination sphere of the rhenium atom is a distorted octahedron, with a ReN bond length of 1.66(1) A. The strong trans influence of the nitrido group is evident in the exceptionally long ReN bond distance (2.42(1) A) to the CH 3 CN ligand." @default.
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- W2000320624 date "1994-10-01" @default.
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- W2000320624 title "Isothiocyanato complexes of rhenium III. Synthesis and characterization of [ReN(NCS)2(Ph3P)2] and [ReN(NCS)2(CH3CN)(Ph3P)2]. X-ray crystal structure of [ReN(NCS)2(CH3CN)(Ph3P)2]·CH3CN" @default.
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- W2000320624 doi "https://doi.org/10.1016/0020-1693(94)04120-2" @default.
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