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- W2000323932 abstract "The zirconium benzamidinate dimethyl complex [PhC(NSiMe3)2]2Zr(Me)2 (1) was activated by a mixture of trityl tetrakispentafluorophenylborate (TTPB) and a small amount of methylalumoxane (MAO) (Zr:B:Al = 1:1:50), forming an extremely active catalytic system for the polymerization of olefins, producing high-density polyethylene and elastomeric polypropylene with a narrow MWD. This catalytic system rivals the activity of the best nonmetallocene systems and approaches the activities of the best metallocene complexes. Single active sites are obtained only after the addition of propylene. A plausible activation mechanism is proposed, which is corroborated by NMR, ESR spectroscopy, radical trapping on fullerene, and MALDI-TOF mass spectroscopy experiments." @default.
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- W2000323932 date "2006-04-26" @default.
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- W2000323932 title "Unusual Synergetic Effect of Cocatalysts in the Polymerization of Propylene by a Zirconium Bis(benzamidinate) Dimethyl Complex" @default.
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- W2000323932 doi "https://doi.org/10.1021/om0602815" @default.
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