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- W2000324529 abstract "Dielectric constants ε of gaseous argon, carbon dioxide and ethylene have been measured by a bridge method with a precision of about 0.3 parts per million at temperatures of 50, 100 and 150°C in the density range 0 to 4 mole liter−1, and the results have been fitted to the dielectric virial equation ε−ε+2Vn=A+B(nV)+C(nV)2, where Vn is the molar volume, and the virial coefficients A, B and C result from polarization of single molecules, pairs and triplets. Temperature independent values of A in cm3-mole−1 are 4.1368 ± 0.0012 for argon, 7.343 ± 0.003 for carbon dioxide and 10.771 ± 0.012 for ethylene. For argon, B was found to be 2.6 ± 0.4 cm6-mole−2 with no detectable temperature dependence. For carbon dioxide, values of B are 41 ± 1(50°), 34 ± 2(100°) and 30 ± 2 cm6-mole−2 (150°); these values are satisfactorily accounted for by a molecular quadropole moment Q = 4.8 × 10−26 esu. For ethylene the values are 54 ± 2 (50°, 51 ± 1 (100°) and 60 ± 1 (150°). These are not consistent with classical calculations and the possible importance of quantum effects is discussed." @default.
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- W2000324529 date "1965-12-01" @default.
- W2000324529 modified "2023-09-23" @default.
- W2000324529 title "Dielectric constants and pair interactions in argon, carbon dioxide and ethylene" @default.
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- W2000324529 doi "https://doi.org/10.1016/0031-8914(65)90099-6" @default.
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