Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000324602> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2000324602 endingPage "274" @default.
- W2000324602 startingPage "269" @default.
- W2000324602 abstract "Abstract The 13C NMR spectra of a series of N-acyl six-member ring nitrogen heterocycles have been measured as a function of temperature and the results interpreted in terms of restricted amide rotation and ring inversion. Slow rotation is observed on the NMR time scale around the N-CO bond whilst the ring inversion is fast at ambient temperature. High temperature experiments have been undertaken to investigate the free energy of activation for the amide rotation and low temperature NMR experiments were used to probe the ring inversion process. The experimental results have been compared with theoretical calculations using molecular orbital, molecular mechanics and molecular dynamics approaches and good agreement is observed in all cases." @default.
- W2000324602 created "2016-06-24" @default.
- W2000324602 creator A5003705877 @default.
- W2000324602 creator A5014283781 @default.
- W2000324602 creator A5028056295 @default.
- W2000324602 creator A5042396446 @default.
- W2000324602 date "1998-03-01" @default.
- W2000324602 modified "2023-09-27" @default.
- W2000324602 title "Molecular Flexibility ofN-Acyl Heterocycles Studied Using 13C NMR Spectroscopy and Computational Chemistry" @default.
- W2000324602 cites W1979126133 @default.
- W2000324602 cites W2003454613 @default.
- W2000324602 cites W2008517160 @default.
- W2000324602 cites W2014758825 @default.
- W2000324602 cites W2021380145 @default.
- W2000324602 cites W2126033468 @default.
- W2000324602 cites W2166417908 @default.
- W2000324602 cites W3004969213 @default.
- W2000324602 doi "https://doi.org/10.1080/00387019808003251" @default.
- W2000324602 hasPublicationYear "1998" @default.
- W2000324602 type Work @default.
- W2000324602 sameAs 2000324602 @default.
- W2000324602 citedByCount "2" @default.
- W2000324602 crossrefType "journal-article" @default.
- W2000324602 hasAuthorship W2000324602A5003705877 @default.
- W2000324602 hasAuthorship W2000324602A5014283781 @default.
- W2000324602 hasAuthorship W2000324602A5028056295 @default.
- W2000324602 hasAuthorship W2000324602A5042396446 @default.
- W2000324602 hasConcept C121332964 @default.
- W2000324602 hasConcept C122873222 @default.
- W2000324602 hasConcept C139358910 @default.
- W2000324602 hasConcept C147597530 @default.
- W2000324602 hasConcept C163111631 @default.
- W2000324602 hasConcept C178790620 @default.
- W2000324602 hasConcept C185592680 @default.
- W2000324602 hasConcept C25057246 @default.
- W2000324602 hasConcept C2778439535 @default.
- W2000324602 hasConcept C2780378348 @default.
- W2000324602 hasConcept C32891209 @default.
- W2000324602 hasConcept C32909587 @default.
- W2000324602 hasConcept C48779969 @default.
- W2000324602 hasConcept C537208039 @default.
- W2000324602 hasConcept C59593255 @default.
- W2000324602 hasConcept C62520636 @default.
- W2000324602 hasConcept C66974803 @default.
- W2000324602 hasConcept C71240020 @default.
- W2000324602 hasConceptScore W2000324602C121332964 @default.
- W2000324602 hasConceptScore W2000324602C122873222 @default.
- W2000324602 hasConceptScore W2000324602C139358910 @default.
- W2000324602 hasConceptScore W2000324602C147597530 @default.
- W2000324602 hasConceptScore W2000324602C163111631 @default.
- W2000324602 hasConceptScore W2000324602C178790620 @default.
- W2000324602 hasConceptScore W2000324602C185592680 @default.
- W2000324602 hasConceptScore W2000324602C25057246 @default.
- W2000324602 hasConceptScore W2000324602C2778439535 @default.
- W2000324602 hasConceptScore W2000324602C2780378348 @default.
- W2000324602 hasConceptScore W2000324602C32891209 @default.
- W2000324602 hasConceptScore W2000324602C32909587 @default.
- W2000324602 hasConceptScore W2000324602C48779969 @default.
- W2000324602 hasConceptScore W2000324602C537208039 @default.
- W2000324602 hasConceptScore W2000324602C59593255 @default.
- W2000324602 hasConceptScore W2000324602C62520636 @default.
- W2000324602 hasConceptScore W2000324602C66974803 @default.
- W2000324602 hasConceptScore W2000324602C71240020 @default.
- W2000324602 hasIssue "2" @default.
- W2000324602 hasLocation W20003246021 @default.
- W2000324602 hasOpenAccess W2000324602 @default.
- W2000324602 hasPrimaryLocation W20003246021 @default.
- W2000324602 hasRelatedWork W1981676177 @default.
- W2000324602 hasRelatedWork W2000324602 @default.
- W2000324602 hasRelatedWork W2000564526 @default.
- W2000324602 hasRelatedWork W2073518156 @default.
- W2000324602 hasRelatedWork W2093112645 @default.
- W2000324602 hasRelatedWork W2169352435 @default.
- W2000324602 hasRelatedWork W2603585593 @default.
- W2000324602 hasRelatedWork W3159764434 @default.
- W2000324602 hasRelatedWork W4214945982 @default.
- W2000324602 hasRelatedWork W2181793952 @default.
- W2000324602 hasVolume "31" @default.
- W2000324602 isParatext "false" @default.
- W2000324602 isRetracted "false" @default.
- W2000324602 magId "2000324602" @default.
- W2000324602 workType "article" @default.