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- W2000326046 abstract "Relatively little attention has been paid to molecular aggregation phenomena in structured non-aqueous solvents compared to that devoted to such processes in aqueous media. This paper is a review concerning our work with formamide in place of water. The following observations showed that formamide has sufficient cohesive force to favor molecular aggregation: (1) critical micellar concentrations (c.m.c.) were determined with various ionic and non-ionic surfactants; (2) the phase diagram of CTAB in formamide shows two mesomorphic phases closely resembling those found in aqueous systems; (3) X-ray scattering demonstrated the presence of molecular aggregates, and gave an indication of their structure, and (4) a variety of microemulsions were prepared in formamide. Such non-aqueous microemulsions represent valuable media for synthetic purposes. For example, Diels-Alder reactions, photoamidation of olefins, and the Wacker process can be carried out readily in such media. The observed discontinuities in reaction selectivity indicate the presence of structured phases." @default.
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- W2000326046 title "Aggregation in formamide solution: Reactivity and structure of non-aqueous microemulsions" @default.
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- W2000326046 doi "https://doi.org/10.1016/0166-6622(89)80297-5" @default.
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