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- W2000328972 abstract "Rh-catalyzed π-facial selective intermolecular hydroacylations of norbornenes with salicylaldehyde have been attained. In the reaction with norbornylene, the exo-hydroacylated product was produced because of steric hindrance. In the case of norbornadiene, the endo-product was obtained because of chelation effect. Lastly, because of chelation and remote substituent effects, the product formed in the reaction of 7-tert-butoxynorbornadiene was the endo,syn-product. Deuterium-labeling experiments revealed that the hydroacylation stereoselectively proceeded via endo- and exo-intermediates." @default.
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- W2000328972 date "2005-09-01" @default.
- W2000328972 modified "2023-10-07" @default.
- W2000328972 title "Rh-catalyzed π-facial selective intermolecular hydroacylation of norbornenes" @default.
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- W2000328972 doi "https://doi.org/10.1016/j.tetlet.2005.07.004" @default.
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