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• W2000329344 abstract "SPE Members Abstract in compositional reservoir simulation the ability of an Equation of State to accurately model the phase behavior is evaluated for both the Peng-Robinson and Soave-Redlich-Kwong Equations of Peng-Robinson and Soave-Redlich-Kwong Equations of State. The analysis was performed with pure component systems to circumvent the problem of pseudo-components and to allow a comparison of pseudo-components and to allow a comparison of calculated ternary diagrams with literature values. The initial work was performed with the binary system of methane and n-decane. The relative permeability of the slim tube was determined by the history matching of an immiscible slim tube displacement. The Equations of State were able to simulate the two-component displacements. PVT experiments were run with the three-component system of methane-propane-n-decane to provide data for a phase match of the Equations of State. The Equations of State with these phase matches were not able to simulate the multiple contact miscibility displacements in a slim tube. The sensitivity of the calculated results to the binary interaction coefficients and to the number of numerical grid blocks was studied. Introduction For several years the Peng-Robinson (PR) and Soave-Redlich-Kwong (SRK) Equations of State have been used to characterize hydrocarbon systems in the field of Reservoir Engineering. The majority of the systems studied are hydrocarbon fluids associated with an oil or gas field. These systems are very complex with thousands of hydrocarbon components. To reasonably calculate the phase behavior with the PR or SRK Equation of State, many components must be merged into pseudo-components with some average properties. The manner in which the components are grouped into these pseudo-components and how the pseudo-component's pseudo-components and how the pseudo-component's properties are determined, is a topic of much properties are determined, is a topic of much research-and discussion. When a fluid description, which contains several pseudo-components, has a difficult time matching the experimental phase behavior or a slim tube displacement with an Equation of State, one does not know where the problem lies. There are many choices, such as the distribution of pseudo-components, Tc, PC, and w of pseudo-components, Tc, PC, and w of pseudo-components, binary interaction coefficients or pseudo-components, binary interaction coefficients or the Equations of State themselves. The object of this research is to study the ability of the PR and SRK Equations of State to simulate phase behavior in a simple hydrocarbon system where there are no pseudo-components and where there exists published experimental results of the phase behavior and critical points. In this simplified hydrocarbon system, the number of parameters in the Equations of State available to parameters in the Equations of State available to match the phase behavior are limited. Thus one can easily see how well the PR and SRK Equations of State simulate the experimental results as the available parameters are varied. Ultimately, we will study the hydrocarbon system of methane-propane-n-decane. In preparation of the ternary study, we will look at the binary system of methane and n-decane to determine the relative permeability of the slim tube and to assess the ability of Equations of State to simulate a simple two-component slim type displacement, i.e., methane displacing n-decane. The Ternary system Of C1+C3+n-CIO represents a model real hydrocarbon system where C1 is the light, gas-like, component, C3 is the intermediate component, and n-C10 is the heavy component. Thus this system should behave more like a real oil but is much easier to analyze, i.e., no pseudo-components are necessary and experimental pseudo-components are necessary and experimental (published) ternary phase diagrams are available for comparison." @default.
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• W2000329344 date "1985-09-22" @default.
• W2000329344 modified "2023-10-16" @default.
• W2000329344 title "The Simulation of Phase Behavior and Slim-Tube Displacements With Equations of State" @default.
• W2000329344 doi "https://doi.org/10.2118/14151-ms" @default.
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