Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000333112> ?p ?o ?g. }
- W2000333112 endingPage "1159" @default.
- W2000333112 startingPage "1152" @default.
- W2000333112 abstract "Using infrared vibrational spectroscopy, we have studied the chemical reactivity of methanol on Ru(0001) under experimental conditions closer to real catalysts than those existing in most of the literature. We have performed experiments in the pressure range from 10− 8 to 10− 3 mbar, exposing the surface to large gas doses at room temperature. We show the co-existence of two active paths: one involves the complete dehydrogenation of methanol into CO, the other one promotes the scission of the CO bond of methanol, leaving carbon and oxygen on the surface, which, after large exposures, deactivate the surface towards a further evolution of the molecular adlayer. In no case, the presence of stable reaction intermediates is detected along either of the two reaction paths. We have compared the behavior of flat ruthenium surfaces with those having a variable concentration of controlled surface defects. Surface defects, mainly steps, seem to accelerate the rate of both reaction paths, but do not activate any new reaction path or stabilize intermediates." @default.
- W2000333112 created "2016-06-24" @default.
- W2000333112 creator A5024242070 @default.
- W2000333112 creator A5080766126 @default.
- W2000333112 date "2012-08-01" @default.
- W2000333112 modified "2023-10-14" @default.
- W2000333112 title "Methanol decomposition on Ru(0001) during continuous exposure at room temperature" @default.
- W2000333112 cites W1857739745 @default.
- W2000333112 cites W1970278786 @default.
- W2000333112 cites W1978052750 @default.
- W2000333112 cites W1980997689 @default.
- W2000333112 cites W1992186379 @default.
- W2000333112 cites W1993017753 @default.
- W2000333112 cites W1993828414 @default.
- W2000333112 cites W1997587374 @default.
- W2000333112 cites W2001887061 @default.
- W2000333112 cites W2004306229 @default.
- W2000333112 cites W2008279120 @default.
- W2000333112 cites W2010350542 @default.
- W2000333112 cites W2010851870 @default.
- W2000333112 cites W2011494591 @default.
- W2000333112 cites W2011718954 @default.
- W2000333112 cites W2012536320 @default.
- W2000333112 cites W2017766785 @default.
- W2000333112 cites W2019594015 @default.
- W2000333112 cites W2032327927 @default.
- W2000333112 cites W2033080992 @default.
- W2000333112 cites W2035618469 @default.
- W2000333112 cites W2042487847 @default.
- W2000333112 cites W2043083344 @default.
- W2000333112 cites W2049103108 @default.
- W2000333112 cites W2060851615 @default.
- W2000333112 cites W2069273771 @default.
- W2000333112 cites W2069642617 @default.
- W2000333112 cites W2072505545 @default.
- W2000333112 cites W2073904273 @default.
- W2000333112 cites W2073958470 @default.
- W2000333112 cites W2076742177 @default.
- W2000333112 cites W2081026140 @default.
- W2000333112 cites W2081668258 @default.
- W2000333112 cites W2082753782 @default.
- W2000333112 cites W2083145308 @default.
- W2000333112 cites W2088385491 @default.
- W2000333112 cites W2113109242 @default.
- W2000333112 cites W2121686777 @default.
- W2000333112 cites W2136336335 @default.
- W2000333112 cites W2146269326 @default.
- W2000333112 cites W2156277291 @default.
- W2000333112 doi "https://doi.org/10.1016/j.susc.2012.02.013" @default.
- W2000333112 hasPublicationYear "2012" @default.
- W2000333112 type Work @default.
- W2000333112 sameAs 2000333112 @default.
- W2000333112 citedByCount "8" @default.
- W2000333112 countsByYear W20003331122012 @default.
- W2000333112 countsByYear W20003331122013 @default.
- W2000333112 countsByYear W20003331122014 @default.
- W2000333112 countsByYear W20003331122017 @default.
- W2000333112 countsByYear W20003331122020 @default.
- W2000333112 countsByYear W20003331122022 @default.
- W2000333112 countsByYear W20003331122023 @default.
- W2000333112 crossrefType "journal-article" @default.
- W2000333112 hasAuthorship W2000333112A5024242070 @default.
- W2000333112 hasAuthorship W2000333112A5080766126 @default.
- W2000333112 hasConcept C119889771 @default.
- W2000333112 hasConcept C121332964 @default.
- W2000333112 hasConcept C124681953 @default.
- W2000333112 hasConcept C142724271 @default.
- W2000333112 hasConcept C147789679 @default.
- W2000333112 hasConcept C153642686 @default.
- W2000333112 hasConcept C161790260 @default.
- W2000333112 hasConcept C175113610 @default.
- W2000333112 hasConcept C178790620 @default.
- W2000333112 hasConcept C185592680 @default.
- W2000333112 hasConcept C204787440 @default.
- W2000333112 hasConcept C2776910235 @default.
- W2000333112 hasConcept C2779607525 @default.
- W2000333112 hasConcept C3044715 @default.
- W2000333112 hasConcept C39353612 @default.
- W2000333112 hasConcept C512735826 @default.
- W2000333112 hasConcept C540031477 @default.
- W2000333112 hasConcept C555196967 @default.
- W2000333112 hasConcept C71924100 @default.
- W2000333112 hasConcept C75473681 @default.
- W2000333112 hasConcept C97355855 @default.
- W2000333112 hasConceptScore W2000333112C119889771 @default.
- W2000333112 hasConceptScore W2000333112C121332964 @default.
- W2000333112 hasConceptScore W2000333112C124681953 @default.
- W2000333112 hasConceptScore W2000333112C142724271 @default.
- W2000333112 hasConceptScore W2000333112C147789679 @default.
- W2000333112 hasConceptScore W2000333112C153642686 @default.
- W2000333112 hasConceptScore W2000333112C161790260 @default.
- W2000333112 hasConceptScore W2000333112C175113610 @default.
- W2000333112 hasConceptScore W2000333112C178790620 @default.
- W2000333112 hasConceptScore W2000333112C185592680 @default.
- W2000333112 hasConceptScore W2000333112C204787440 @default.
- W2000333112 hasConceptScore W2000333112C2776910235 @default.
- W2000333112 hasConceptScore W2000333112C2779607525 @default.
- W2000333112 hasConceptScore W2000333112C3044715 @default.