Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000335192> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2000335192 endingPage "356" @default.
- W2000335192 startingPage "345" @default.
- W2000335192 abstract "The water-gas shift reaction over an industrial ferrochrome catalyst (ICI 15-4) was studied by transient experiments in a gradientless spinning basket reactor at 563–638 K and atmospheric pressure. The responses of CO, CO2, and H2 were measured after step changes at the reactor inlet. The stationary kinetics were described with a first-order rate expression with respect to CO. The rate constants were determined at four temperatures. The CO2 responses followed approximately a first-order behavior, whereas the dynamics of the H2 liberation was always slower than the CO2 evolution. Hydrogen formation was retarded by H2O pretreatment of the catalyst. Two characteristic values of the total oxygen transfer through the catalyst were determined from the CO2 and H2 responses, corresponding to the catalyst pretreatments with the reactive gases (CO and H2O) and with H2O. The transient responses were modeled with a reaction mechanism involving rapid water adsorption and slow CO interconversion and H2 desorption steps. The kinetic parameters of the simplified dynamic model were determined by regression analysis. The shift reactor start-up and shut-down could be predicted by the dynamic model developed." @default.
- W2000335192 created "2016-06-24" @default.
- W2000335192 creator A5079065398 @default.
- W2000335192 date "1988-08-01" @default.
- W2000335192 modified "2023-09-23" @default.
- W2000335192 title "A dynamic study of the water-gas shift reaction over an industrial ferrochrome catalyst" @default.
- W2000335192 cites W1515753772 @default.
- W2000335192 cites W1970251532 @default.
- W2000335192 cites W1976683184 @default.
- W2000335192 cites W1991581182 @default.
- W2000335192 cites W1998038478 @default.
- W2000335192 cites W2051350954 @default.
- W2000335192 cites W2062668730 @default.
- W2000335192 cites W2073123687 @default.
- W2000335192 cites W2078932319 @default.
- W2000335192 cites W2086574974 @default.
- W2000335192 cites W2090994744 @default.
- W2000335192 cites W2143452738 @default.
- W2000335192 cites W567683744 @default.
- W2000335192 doi "https://doi.org/10.1016/0021-9517(88)90148-0" @default.
- W2000335192 hasPublicationYear "1988" @default.
- W2000335192 type Work @default.
- W2000335192 sameAs 2000335192 @default.
- W2000335192 citedByCount "28" @default.
- W2000335192 countsByYear W20003351922012 @default.
- W2000335192 countsByYear W20003351922015 @default.
- W2000335192 countsByYear W20003351922016 @default.
- W2000335192 countsByYear W20003351922017 @default.
- W2000335192 countsByYear W20003351922018 @default.
- W2000335192 countsByYear W20003351922019 @default.
- W2000335192 countsByYear W20003351922022 @default.
- W2000335192 countsByYear W20003351922023 @default.
- W2000335192 crossrefType "journal-article" @default.
- W2000335192 hasAuthorship W2000335192A5079065398 @default.
- W2000335192 hasConcept C121332964 @default.
- W2000335192 hasConcept C147789679 @default.
- W2000335192 hasConcept C148898269 @default.
- W2000335192 hasConcept C150394285 @default.
- W2000335192 hasConcept C161790260 @default.
- W2000335192 hasConcept C162711632 @default.
- W2000335192 hasConcept C175113610 @default.
- W2000335192 hasConcept C178790620 @default.
- W2000335192 hasConcept C185592680 @default.
- W2000335192 hasConcept C194439259 @default.
- W2000335192 hasConcept C204242273 @default.
- W2000335192 hasConcept C2778254334 @default.
- W2000335192 hasConcept C36663273 @default.
- W2000335192 hasConcept C511782168 @default.
- W2000335192 hasConcept C512735826 @default.
- W2000335192 hasConcept C512968161 @default.
- W2000335192 hasConcept C540031477 @default.
- W2000335192 hasConcept C62520636 @default.
- W2000335192 hasConcept C65024703 @default.
- W2000335192 hasConcept C66114498 @default.
- W2000335192 hasConcept C67334161 @default.
- W2000335192 hasConcept C97355855 @default.
- W2000335192 hasConceptScore W2000335192C121332964 @default.
- W2000335192 hasConceptScore W2000335192C147789679 @default.
- W2000335192 hasConceptScore W2000335192C148898269 @default.
- W2000335192 hasConceptScore W2000335192C150394285 @default.
- W2000335192 hasConceptScore W2000335192C161790260 @default.
- W2000335192 hasConceptScore W2000335192C162711632 @default.
- W2000335192 hasConceptScore W2000335192C175113610 @default.
- W2000335192 hasConceptScore W2000335192C178790620 @default.
- W2000335192 hasConceptScore W2000335192C185592680 @default.
- W2000335192 hasConceptScore W2000335192C194439259 @default.
- W2000335192 hasConceptScore W2000335192C204242273 @default.
- W2000335192 hasConceptScore W2000335192C2778254334 @default.
- W2000335192 hasConceptScore W2000335192C36663273 @default.
- W2000335192 hasConceptScore W2000335192C511782168 @default.
- W2000335192 hasConceptScore W2000335192C512735826 @default.
- W2000335192 hasConceptScore W2000335192C512968161 @default.
- W2000335192 hasConceptScore W2000335192C540031477 @default.
- W2000335192 hasConceptScore W2000335192C62520636 @default.
- W2000335192 hasConceptScore W2000335192C65024703 @default.
- W2000335192 hasConceptScore W2000335192C66114498 @default.
- W2000335192 hasConceptScore W2000335192C67334161 @default.
- W2000335192 hasConceptScore W2000335192C97355855 @default.
- W2000335192 hasIssue "2" @default.
- W2000335192 hasLocation W20003351921 @default.
- W2000335192 hasOpenAccess W2000335192 @default.
- W2000335192 hasPrimaryLocation W20003351921 @default.
- W2000335192 hasRelatedWork W1972215728 @default.
- W2000335192 hasRelatedWork W2020799357 @default.
- W2000335192 hasRelatedWork W2040296114 @default.
- W2000335192 hasRelatedWork W2094565162 @default.
- W2000335192 hasRelatedWork W2095243215 @default.
- W2000335192 hasRelatedWork W2130891706 @default.
- W2000335192 hasRelatedWork W2213060703 @default.
- W2000335192 hasRelatedWork W2564080144 @default.
- W2000335192 hasRelatedWork W294673352 @default.
- W2000335192 hasRelatedWork W809657555 @default.
- W2000335192 hasVolume "112" @default.
- W2000335192 isParatext "false" @default.
- W2000335192 isRetracted "false" @default.
- W2000335192 magId "2000335192" @default.
- W2000335192 workType "article" @default.