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- W2000337836 abstract "The electronic structure of a cobalt iron cyanide thin film, Na0.4Co1.3[Fe(CN)6]5H2O, was switched from FeIII(low spin)−CN−CoII(high spin) to FeII(low spin)−CN−CoIII(low spin) by exchanging cations in interstitial sites from Na+ to K+. The reverse process was also induced by replacing Na+ with K+. That is, the alkali cations in the interstitial sites dominate the electronic and spin states of the host compound. This type of switching phenomenon can be achieved by choosing a compound with both electronic degeneracy and zeolitic properties." @default.
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- W2000337836 date "1997-05-01" @default.
- W2000337836 modified "2023-10-18" @default.
- W2000337836 title "Cation-Driven Electron Transfer Involving a Spin Transition at Room Temperature in a Cobalt Iron Cyanide Thin Film" @default.
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- W2000337836 doi "https://doi.org/10.1021/jp9701451" @default.
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