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• W2000346188 abstract "Asymmetric hydrogenation of ketone 1 using trans-RuCl(2)[(R)-xylbinap][(R)-daipen] (3) as a catalyst afforded secondary alcohol 2 quantitatively and in 99.4% ee. Further exploration of the effect of the thiazole ring substitution revealed that the catalyst was highly effective for the enantioselective hydrogenation of 5-benzoyl thiazoles, which afforded corresponding alcohols in 92-99% ee. The same protocol was applicable to a variety of aromatic-heteroaromatic ketones to generate secondary alcohols in excellent enantioselectivities. [reaction: see text]" @default.
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• W2000346188 date "2003-11-27" @default.
• W2000346188 modified "2023-10-07" @default.
• W2000346188 title "Highly Enantioselective Hydrogenation of Aromatic-Heteroaromatic Ketones" @default.
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• W2000346188 doi "https://doi.org/10.1021/ol0360795" @default.
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