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- W2000347930 abstract "The radicals formed from photolysis of aqua(alkyl)cobaloximes (R = sec-C4H9, n-C4H9, i-C4H9, c-C5H9 or c-C6H11) in the absence and presence of β-cyclodextrin at room temperature have been characterized by the EPR spin trapping technique using 2-methyl-2-nitrosopropane. It has been found that only the primary alkyl radicals produced by Co–C bond cleavage of the cobaloximes during photolysis undergo 1,2-rearrangement reactions. The spin adducts formed can be included in the cavity of β-cyclodextrin, which plays an important role in stabilizing the primary alkyl radicals." @default.
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- W2000347930 date "2001-01-01" @default.
- W2000347930 modified "2023-10-18" @default.
- W2000347930 title "Spin trapping EPR investigation of the photolysis of aqua(alkyl)cobaloximes: 1,2-rearrangement reactions of photo-induced primary radicals and β-cyclodextrin's stabilizing effects" @default.
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- W2000347930 doi "https://doi.org/10.1039/b009972o" @default.
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