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- W2000352163 abstract "Synthesis of N-Sulfinylprotected Aminobenzylhalides and Reactions with Nucleophiles N-Sulfinylaminotoluenes 3 react with sulfuryl chloride or N-bromosuccinimide to give N-sulfinylaminobenzylchlorides 4 and N-sulfinylaminobenzylbromides 5, respectively. o-N-Sulfinylaminobenzylchloride 4 a can also be synthesized by the reaction of o-aminobenzylalcohol 6 with thionyl chloride. Nucleophiles react with benzylhalides 4 and 5 to form aminobenzyl ethers, thioethers, and amines 7–9. Tetrahydrochinazolinethione 11 can be formed by the reaction of 4 a or 5 a with thiocyanate ions followed by the hydrolysis of intermediate 10." @default.
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- W2000352163 date "1981-01-01" @default.
- W2000352163 modified "2023-09-23" @default.
- W2000352163 title "Synthese von N-sulfinylgeschützten Aminobenzylhalogeniden und Umsetzung mit Nucleophilen" @default.
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- W2000352163 doi "https://doi.org/10.1002/prac.19813230319" @default.
- W2000352163 hasPublicationYear "1981" @default.
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