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- W2000354827 abstract "Abstract The infrared multiphoton dissociation of 2-chloroethenylsilane induced by a tunable CO 2 laser, under both collision-free and collisional conditions, results in an intense visible luminescence. Spectral analysis of this emission was carried out, and a broad, structureless band, centered at about 650 nm, was obtained. The intensity of this luminescence was studied in relation to multiphoton dissociation as a function of the gas pressure and the frequency and fluence of the laser beam. Lifetime measurements of the luminescence were performed for different pressures of the parent molecule, and the radiative decay time was found to be 480 ± 20 ns. The quenching rate of this emission by homogeneou collisions is (1.44 ± 0.08) × 10 −10 cm 3 molecule −1 s −1 . The luminescence was assigned to decay from the if 1 B 1 electronic state to the 1 B 1 ground state of silylene formed within the laser pulse. The detection of silylene supports the previously postulated reaction pathways in the infrared multiphoton dissociation of 2-chloroethenylsilane. It also suggests that, at high fluence conditions, the chloroethane elimination channel dominates the dissociation reaction." @default.
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- W2000354827 date "1997-04-01" @default.
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- W2000354827 title "Visible luminescence study of the infrared multiphoton dissociation of 2-chloroethenylsilane" @default.
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- W2000354827 doi "https://doi.org/10.1016/s1010-6030(97)00004-x" @default.
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