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• W2000355243 abstract "Nanoscale molecular rotors that can be driven in the solid state have been realized in Cs2([18]crown-6)3[Ni(dmit)2]2 crystals. To provide interactions between the molecular motion of the rotor and the electronic system, [Ni(dmit)2]- ions, which bear one S = 1/2 spin on each molecule, were introduced into the crystal. Rotation of the [18]crown-6 molecules within a Cs2([18]crown-6)3 supramolecule above 220 K was confirmed using X-ray diffraction, NMR, and specific heat measurements. Strong correlations were observed between the magnetic behavior of the [Ni(dmit)2]- ions and molecular rotation. Furthermore, braking of the molecular rotation within the crystal was achieved by the application of hydrostatic pressure." @default.
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• W2000355243 date "2005-02-26" @default.
• W2000355243 modified "2023-10-17" @default.
• W2000355243 title "Molecular Rotor of Cs₂([18]crown-6)₃ in the Solid State Coupled with the Magnetism of [Ni(dmit)₂]" @default.
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• W2000355243 doi "https://doi.org/10.1021/ja043527a" @default.
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