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- W2000355723 abstract "Compounds such as α-phenyl(mercapto)tetrazole (PMT) oxime (9) undergo rapid elimination of the PMT anion in base via a nitrosoene intermediate. Solution kinetics and HPLC analysis of reaction products are consistent with the mechanism shown in Scheme 2. For open chain oximes such as 4, substitution α to the oxime increases the rate of release of PMT and is attributed to the relief of strain when a crowded reactant is converted to a less-crowded product. For cyclic oximes, the six-membered ring compounds are more reactive than the corresponding five-membered compounds. A linear isokinetic relationship between the entropy and enthalpy of activation was found with β= 346 ± 51 K. Entropies of activation were found to range from –7 to +24 c.u. (1 c.u. = 4.184 J mol–1 K–1) and support the proposed mechanism." @default.
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- W2000355723 date "1992-01-01" @default.
- W2000355723 modified "2023-10-14" @default.
- W2000355723 title "Kinetics and mechanism of the alkaline release of phenyl(mercapto)tetrazoles from α-oximes" @default.
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- W2000355723 doi "https://doi.org/10.1039/p29920001271" @default.
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