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- W2000358524 abstract "The vibrational spectra of the NH2 stretching modes of the aniline−furan complex and its cation in a supersonic jet have been measured by infrared depletion spectroscopic methods. Two absorption bands have been observed at 3409 and 3497 cm-1 in the spectrum of the neutral aniline−furan complex, which is red-shifted from the corresponding bands of aniline monomer by 12 and 11 cm-1, respectively. The main intermolecular interaction of the complex has been found to be a weak hydrogen bond between the NH bond of aniline and the lone pair of the oxygen atom of furan. As for the aniline−furan cation complex, two strong absorption bands have been observed at 3315 and 3446 cm-1 in the infrared spectrum. In this case, the main intermolecular interaction has been found to be the NH-π type hydrogen bond between one of the NH bonds and the π-electron of the aromatic ring of furan. The difference between the interactions of the neutral and the cation complexes has been discussed." @default.
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- W2000358524 date "1999-06-30" @default.
- W2000358524 modified "2023-09-23" @default.
- W2000358524 title "Investigations on the Hydrogen Bond Interaction in the Aniline−Furan Complex and Its Cation by Infrared Depletion Spectroscopy" @default.
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- W2000358524 doi "https://doi.org/10.1021/jp983631c" @default.
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